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TCP/IP network Since these are usually specialized computers from many manufacturers, it would be dif cult to get into speci cs for all the variations and iterations, so consider this a familiarization with the requirements to make a Unix-based computer network-able Unix is a at le operating system, which basically means RANDOM BONUS DEFINITION that most of the con guration trap A message that originates from a les are in readable text Con gnetwork management client to a network uration is accomplished using management server to notify the server of a one of the resident text procesnotable event sor programs that are part of the utilities that come with the operating system The appropriate les can be edited as needed to con gure the TCP/IP settings on the computer Usually, systems of this vintage have system administrators who maintain and update the /etc/hosts22 le.

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semiotic requirements for coordination have to do with the development of a language that the cooperating actors understand, hand in hand with a structuring of the shared information eld in objects, properties, actions, and so on. The latter structuring can be described in a theoretical way as an ontology. The characteristics of the language can be theoretically described based on its syntactics, semantics, and pragmatics. With respect to syntactics, multi-actor systems need a language that is structured with the help of syntactical rules and a lexicon. Specialized actor languages (Wooldridge, 2002, p. 168) have been developed for multi-agent systems. In the eld of semantics, multi-actor systems need a common ontology (Wooldridge, 2002, p. 180). In the domain of pragmatics, multi-actor systems need protocols for de ning and assigning tasks and standard protocols of interaction (Dietz, 1992, 1996). Information systems need protocols for the handling and routing of events, queries, and messages (pragmatics) (Gazendam, 1997). Recurrent patterns of language interaction can be studied as genres or work practices (Clarke, 2001) or iterators (B gh Andersen, Nielsen, and Land, 1999). The regionalization theory says that trajectories in time and space of the daily, weekly, monthly, and overall life paths of individuals in interaction with each other create a space and time structure in the shared semiotic Umwelt (Hagerstrand, 1975; Giddens, 1984, p. 112):

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The lower electronic states of the reactants (left-hand side) are those of the carbonyl group shown in Figure 148c, since the sCH and sCH orbitals are too far apart to participate in the lower electronic states In other words, the light will be absorbed by the carbonyl compound The local group orbitals of the product fragments and the states which arise from them are shown in Figure 154 The reaction is considered to take place in the plane of the carbonyl group, and the orbitals are symmetry typed according to their behavior with respect to re ection in this plane A Dauben Salem Turro state correlation diagram for the photochemical step of the Norrish Type II hydrogen abstraction reaction is shown in Figure 155 The reactant (carbonyl) states are classi ed in point group Cs and also as S or A.

The placement of the reactant and product states on the same energy diagram need only be approximate The singlet and triplet np states are located by virtue of the observed lowest electronic transition in the UV spectra of carbonyls, about 250 nm or 5 eV relative to the ground state The pp states are higher, with a larger singlet triplet gap Assuming the ground states of reactants and products to be of similar energy, the diradical states may be placed at about the energy required to dissociate a C C or C H bond, about 360 kJ/mol or 4 eV The state correlation diagram indicates that the reaction should proceed via the np states which correlate directly with the product states of the respective multiplicity The pp states of the carbonyl group correlate with higher electronic states of the products.

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The carbonyl ground state correlates with the Z1 state of products Both singlet and triplet np states cross with the ascending ground state at the regions marked by shaded circles At the crossing of singlet states, IC may allow a substantial fraction of the reaction to revert to the reactants Intersystem crossing is usually much less e cient, and therefore a higher quantum yield would result if the reaction were carried out on the triplet potential energy surface The e ciency of photon capture to form the 1 np state is very low since the excitation is electric dipole forbidden in the local C2v point group of the carbonyl Direct.